Here are the matches for the sentences with the corresponding times:

1. I get up at six o'clock in the morning.
**b. 6 am**

2. I go to work at eight thirty in the morning.
**e. 8:30 am**

3. I finish work at five thirty in the afternoon.
**a. 5:30 pm**

4. I get home at six ten.
**c. 6:10 pm**

5. I relax and watch TV at seven thirty in the evening.
**f. 7:30 pm**

6. I go to bed at ten forty-five at night.
**d. 10:45 pm**